Can mechanochemistry be used to control reaction selectivity?

We develop a general theoretical and computational framework based on a nonlinear Onsager's formalism of irreversible thermodynamics for the dynamics of curved ... For centuries, apothecaries made medicines by blending together specific ratios of crushed ingredients or “simples,” including medicinal plants, minerals, and ... We introduce in situ energy-dispersive X-ray diffraction (EDXRD) monitoring of reactive extrusion to help industrial implementation of mechanochemistry. This ... Sep 14, 2018 ... Because the dissociation produces highly reactive and redox active products with differential properties, ferrocene might be a useful ... Citation: V. V. Boldyrev, E. G. Avvakumov, “Mechanochemistry of Inorganic Solids”, Usp. Khim., 40:10 (1971), 1835–1856; Russian Chem. Reviews, 40:10 (1971) ... Mechanochemistry is a subject that embraces many everyday phenomena including wear and abrasion, friction and lubrication, and stress-accelerated degradation ... The application of mechanical force to influence chemical reactions has been called by various names: mechanochemistry, tribochemistry, mechanical alloying, to ... Jun 19, 2023 ... While the concept of mechanochemistry is not new, it is becoming significantly more prevalent in a wide variety of fundamental and ... Mechanochemistry employs mechanophores (force-sensitive molecules) to produce chemical changes in a material in response to an applied mechanical force. Sep 11, 2017 ... Mechanochemical syntheses of heterocyclic rings, multicomponent reactions and organometallic molecules including their catalytic applications are also ...