What is the relative reactivity of different acylating agents? How does the leaving group affect the rate of acylation?

Mar 19, 2023 ... Question: What is the correct order of events in lab session 1 (see slide 4 and notes page)? Boc installation, neutralization, acylation ... Thus, while the Friedel-Crafts acylation of benzene requires aluminum chloride as a catalyst, ferrocene can be acylated by acetic anhydride under milder ... S-acylation results from the enzymatic addition of long-chain lipids, most typically palmitate, onto intracellular cysteine residues of soluble and ... Our results from using mass spectrometry (MS) show that influenza B virus HA possessing two cytoplasmic cysteines contains palmitate. ... acylation of the amino and alcohol radicals of the starting material. This reference teaches that ease of acylation follows the descending order: primary ... acidic conditions, 1-acyl triazenes act as acylation reagents. ... acylation reactions with the brominated triazene 23. With water and methanol ... Acylation Derivatization Reagent, TFAA (Trifluoroacetic Acid Anhydride), 10x1 g Vials, 10-pk. Apr 30, 2024 ... Acylation is the process of integrating an acyl group (RCO-) into a specific compound. This reaction primarily involves the substitution of a nucleophile. Acylation: A reaction in which an acyl group is added to a molecule. In this example of the Friedel-Crafts acylation reaction, benzene is acylated with ... eLife assessment. This paper makes a valuable contribution by implicating S-acylation of Cys-130 in recruitment of the inflammasome receptor NLRP3 to the ...